默尼科技，專業(yè)提供DEME TFSI產(chǎn)品及其技術(shù)

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The room‐temperature molten salt mixture of N,N‐diethyl‐N‐(2‐methoxyethyl)‐N‐methylammonium bis(trifluoromethanesulfonyl) imide ([DEME][TFSI]) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt is herein reported as electrolyte for application in Li–O₂ batteries. The [DEME][TFSI]–LiTFSI solution is studied in terms of ionic conductivity, viscosity, electrochemical stability, and compatibility with lithium metal at 30?°C, 40?°C, and 60?°C. The electrolyte shows suitable properties for application in Li–O₂ battery, allowing a reversible, low‐polarization discharge–charge performance with a capacity of about 13?Ah?gin the positive electrode and coulombic efficiency approaching 100?%. The reversibility of the oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) is demonstrated by ex?situ XRD and SEM studies. Furthermore, the study of the cycling behavior of the Li–O₂ cell using the [DEME][TFSI]‐LiTFSI electrolyte at increasing temperatures (from 30 to 60?°C) evidences enhanced energy efficiency together with morphology changes of the deposited species at the working electrode. In addition, the use of carbon‐coated Zn_0.9Fe_0.1O (TMO‐C) lithium‐conversion anode in an ionic‐liquid‐based Li‐ion/oxygen configuration is preliminarily demonstrated.